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Angelina Jolie on her new film

In a rare television interview, Angelina Jolie sits down exclusively with NBC News' Ann Curry to discuss her upcoming movie, "A Mighty Heart," in which she plays Mariane Pearl, the wife of Daniel Pearl, the Wall Street Journal reporter who was murdered by terrorists in Pakistan in 2002. Click here for a transcript.

In a separate interview, Brad Pitt talks to Curry about his behind-the-scenes role as a producer in "A Mighty Heart," which is produced by his Plan B shingle in conjunction with Revolution films.  Dede Gardner and Andrew Eaton, two producers of the movie, will also join Pitt in the interview.

 Hollywood couple Angelina Jolie (R) and

The interviews will air on NBC News' "Today" and "Dateline NBC" Wednesday, May 23.